Cyclic Carbonate Synthesis from Epoxides and CO2 Catalyzed by Aluminum-Salen Complexes Bearing a nido-C2B9 Carborane Ligand.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00797
Abstract: The active and well-designed Schiff base ligands are considered "privileged ligands". The so-called salen ligands, i.e., the tetradentate [O, N, N, O] bis-Schiff base ligands, have also found broad applications in many homogeneous catalytic reactions.… read more here.
Keywords: c2b9 carborane; nido c2b9; aluminum salen; epoxides co2 ... See more keywords
Aluminum Salen Complexes Modified with Unsaturated Alcohol: Synthesis, Characterization, and Their Activity towards Ring-Opening Polymerization of ε-Caprolactone and D,L-Lactide
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28031262
Abstract: A highly efficient one-step approach to the macromonomer synthesis using modified aluminum complexes as catalysts of ring-opening polymerization (ROP) of ε-caprolactone and D,L-lactide was developed. The syntheses, structures, and catalytic activities of a wide range… read more here.
Keywords: caprolactone lactide; caprolactone; opening polymerization; aluminum salen ... See more keywords