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Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc01554d
Abstract: (NONDipp)Al-K(TMEDA)2 (NONDipp = [O(SiMe2NDipp)2]2-, Dipp = 2,6-iPr2C6H3), containing an Al-K bond, activates and reductively couples cabon monoxide gas to form the [C4O4]4- ligand. This oxocarbon anion is thermally isomerised in the presence of CO and…
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Keywords:
c5o5 ligand;
chain growth;
ligand;
aluminyl ... See more keywords
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Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02111k
Abstract: The previously reported potassium aluminyl complex [(BDI-H)Al-K+]2 was converted in Li+ or Na+ salts by a salt metathesis reaction with Li(BPh4) or Na(BPh4), respectively; BDI-H = dianionic [(DIPP)N-C(Me)C(H)-C(CH2)-N(DIPP)2-] and DIPP = 2,6-diisopropylphenyl. The Rb and…
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Keywords:
dipp;
aluminyl;
aluminyl complexes;
bdi ... See more keywords