Reversible [4 + 1] Cycloaddition of Arenes by a “Naked” Acyclic Aluminyl Compound
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DOI: 10.1021/jacs.4c00376
Abstract: The large steric profile of the N-heterocyclic boryloxy ligand, –OB(NDippCH)2, and its ability to stabilize the metal-centered HOMO, are exploited in the synthesis of the first example of a “naked” acyclic aluminyl complex, [K(2.2.2-crypt)][Al{OB(NDippCH)2}2]. This… read more here.
Keywords: aluminyl; acyclic aluminyl; aluminyl compound; naked acyclic ... See more keywords