Remarkable Improvement in Am3+ and Cm3+ Separation Using a Cooperative Counter Selectivity Strategy by a Combination of Branched Diglycolamides and Hydrophilic Polyaza-heterocycles.
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DOI: 10.1021/acs.inorgchem.4c01081
Abstract: Separation of Am3+ and Cm3+ is one of the most challenging problems in the back-end of the nuclear fuel cycle. In the present work, we exploited the cooperative effect of the opposite selectivity of hydrophobic… read more here.
Keywords: separation; cm3 separation; am3 cm3; am3 ... See more keywords
Hexanitrato complexes and hybrid double perovskites of Am3+ and Cm3.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc05162a
Abstract: The synthesis and structures of the homoleptic hexanitrato complexes of Am(III) and Cm(III), [(CH3)4N]2KAn(NO3)6 are reported. These compounds form a double perovskite structure type, A2B'BX6, crystallizing in the cubic space group Fm3̄m. Their electronic properties,… read more here.
Keywords: am3 cm3; hexanitrato complexes; hybrid double; complexes hybrid ... See more keywords