Kinetic evidence for two different active sites on dry Amberlyst® 15 catalyst in the alkylation between 1-dodecene and p-xylene
Sign Up to like & getrecommendations! Published in 2019 at "Reaction Kinetics, Mechanisms and Catalysis"
DOI: 10.1007/s11144-019-01557-1
Abstract: On Amberlyst® 15 catalyst (dry) at 85 °C, 1-dodecene underwent concurrent double bond isomerization and alkylation with p-xylene. The alkylation reaction appeared to occur by an Eley–Rideal mechanism in which adsorbed olefin reacted with bulk phase… read more here.
Keywords: xylene; dodecene; alkylation; amberlyst catalyst ... See more keywords
Olefin esterification on Amberlyst® 15 catalyst: does the esterification site defy thermodynamics?
Sign Up to like & getrecommendations! Published in 2020 at "Reaction Kinetics, Mechanisms and Catalysis"
DOI: 10.1007/s11144-020-01794-9
Abstract: Kinetics for the reaction between 1-tetradecene and heptanoic acid to make tetradecyl heptanoates on dry Amberlyst® 15 catalyst at 90 °C are extremely complex. Observed kinetics of simultaneous double bond isomerization and esterification cannot be… read more here.
Keywords: thermodynamics; esterification; tetradecene; isomerization ... See more keywords
Exergy-based sustainability analysis of acetins synthesis through continuous esterification of glycerol in acetic acid using Amberlyst®36 as catalyst
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Cleaner Production"
DOI: 10.1016/j.jclepro.2018.02.218
Abstract: Abstract This research was devoted to investigating the exergetic performance of a continuous reactor applied to valorize glycerol through esterification with acetic acid in the presence of Amberlyst®36 as catalyst. The main aim of the… read more here.
Keywords: acetic acid; esterification; amberlyst catalyst; glycerol ... See more keywords