Ambiphilicity of a mononuclear cobalt(III) superoxo complex.
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DOI: 10.1039/d0cc05337f
Abstract: Addition of HOTf to a mixture of CoIII(BDPP)(O2˙) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp*2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged… read more here.
Keywords: iii superoxo; coiii; ambiphilicity mononuclear; superoxo complex ... See more keywords