Articles with "americium" as a keyword



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Assay of actinides in human urine by rapid method

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Published in 2017 at "Journal of Radioanalytical and Nuclear Chemistry"

DOI: 10.1007/s10967-017-5363-2

Abstract: A method using DGA resin (N,N,N′,N′-tetra-n-octyldiglycolamide on an inert support) was developed for the rapid analysis of actinides in urine samples. Samples acidified with HCl to 4 M were loaded directly (without digestion) onto a DGA… read more here.

Keywords: assay actinides; human urine; rapid method; urine rapid ... See more keywords

A comparison of curium, neptunium and americium transmutation feasibility

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Published in 2018 at "Annals of Nuclear Energy"

DOI: 10.1016/j.anucene.2017.09.041

Abstract: Abstract Minor actinides transmutation is the process of decreasing the long term radiotoxicity of the nuclear spent fuel by submitting it to a neutron flux so as to achieve fission of the heavy nuclides concerned.… read more here.

Keywords: transmutation; americium; fuel cycle; curium ... See more keywords

Thermophysical properties of (UxAm1−x)O2 MOX fuel

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Published in 2020 at "Computational Materials Science"

DOI: 10.1016/j.commatsci.2019.109324

Abstract: Abstract The effect of the addition of americium on the thermophysical properties of uranium dioxide (UO2) has been systematically studied by molecular dynamics (MD) simulation technique in the whole concentration range of americium and the… read more here.

Keywords: uxam1 mox; properties uxam1; mox fuel; americium ... See more keywords
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Structure and Characterization of an Americium Bis(O,O'-diethyl)dithiophosphate Complex.

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Published in 2020 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.0c02085

Abstract: A facile synthesis of an americium complex with a sulfur-donor ligand has been developed, allowing characterization of americium bonding from multiple perspectives via several techniques. Reaction of 243Am with S2P(OEt)2- yields the tetrakis complex [Am(S2P(OEt)2)4]-… read more here.

Keywords: characterization americium; americium bis; americium; structure characterization ... See more keywords

Ionothermal Synthesis of Am4B22O42Cl12: A Chiral Cubic Americium Borate Cluster.

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Published in 2025 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.4c05455

Abstract: Ionic liquids were used as low temperature solvents for the synthesis of new lanthanide and transuranic-element (TRU) borate cluster structures. Ionothermal synthesis with the ionic liquid [BMIm]Cl (1-butyl-3-methylimidazolium chloride) yielded the La, Nd, and Am… read more here.

Keywords: americium; cluster; ionothermal synthesis; borate cluster ... See more keywords

Kinetics of the Autoreduction of Hexavalent Americium in Aqueous Nitric Acid.

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Published in 2017 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.7b00990

Abstract: The rate of reduction of hexavalent 243Am due to self-radiolysis was measured across a range of total americium and nitric acid concentrations. These so-called autoreduction rates exhibited zero-order kinetics with respect to the concentration of… read more here.

Keywords: nitric acid; rate; hexavalent americium; americium ... See more keywords

Ultra-Efficient Americium/Lanthanide Separation through Oxidation State Control.

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Published in 2022 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.2c00594

Abstract: Lanthanide/actinide separation is a worldwide challenge for atomic energy and nuclear waste treatment. Separation of americium (Am), a critical actinide element in the nuclear fuel cycle, from lanthanides (Ln) is highly desirable for minimizing the… read more here.

Keywords: oxidation; americium; iii; separation ... See more keywords

Cyclopentadienyl coordination induces unexpected ionic Am−N bonding in an americium bipyridyl complex

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Published in 2022 at "Nature Communications"

DOI: 10.1038/s41467-021-27821-4

Abstract: Variations in bonding between trivalent lanthanides and actinides is critical for reprocessing spent nuclear fuel. The ability to tune bonding and the coordination environment in these trivalent systems is a key factor in identifying a… read more here.

Keywords: coordination environment; americium; coordination; cyclopentadienyl coordination ... See more keywords

Extraction and speciation studies of new diglycolamides for selective recovery of americium by solvent extraction

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Published in 2025 at "RSC Advances"

DOI: 10.1039/d5ra00815h

Abstract: Much research has gone into the development of extraction processes capable of separating minor actinides from highly active raffinates generated by the PUREX process. In particular, the separation of americium from curium remains challenging because… read more here.

Keywords: speciation studies; extraction speciation; extraction; selectivity ... See more keywords

Behavior of Americium in Simulated Wounds in Nonhuman Primates

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Published in 2017 at "Health Physics"

DOI: 10.1097/hp.0000000000000658

Abstract: Abstract An americium solution injected intramuscularly into several nonhuman primates (NHPs) was found to behave differently than predicted by the wound models described in the NCRP Report 156. This was because the injection was made… read more here.

Keywords: americium simulated; behavior americium; nonhuman primates; americium ... See more keywords