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Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b04445
Abstract: A new mechanism of La-catalyzed amidation of N-methylbenzylamine with p-chlorobenzaldehyde has been computationally proposed, where L2La[NR1R2] (I) rather than previously proposed L2La[OCHRNR1R2] (II) is the catalytically active species. Interestingly, the side-product alcohol acting as a…
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Keywords:
amidation aldehyde;
catalyzed amidation;
insights catalyzed;
aldehyde amine ... See more keywords