Preparation of two amide bonded stationary phases and comparative evaluation under mixed-mode chromatography.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of separation science"
DOI: 10.1002/jssc.202100291
Abstract: In this work, the conventional reactions were used to functionalize the silica surface with amide and hydrocarbon chain groups affording two different mixed-mode stationary phases (Sil-amide-C11 and Sil-C12-amide). The prepared stationary phases were analyzed by… read more here.
Keywords: chromatography; mixed mode; different interactions; amide ... See more keywords
Synthesis of a Carbene-Stabilized (Diphospha)aminyl Radical and Its One Electron Oxidation and Reduction to Nonclassical Nitrenium and Amide Species.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01408
Abstract: Herein, we report the synthesis of an acyclic carbene-stabilized diphospha(aminyl) PNP radical CAACMePNPCAACMe 4 (CAACMe = 1-[2,6-bis(isopropyl)phenyl]-3,3,5,5-tetramethyl-2-pyrrolidinylidene) by a facile one-pot, seven-electron reduction of hexachlorophosphazene chloride [Cl3PNPCl3][Cl]. The PNP radical 4 features a conjugated framework… read more here.
Keywords: stabilized diphospha; amide; geometry; carbene stabilized ... See more keywords
Chiral nanostructures self-assembled from nitrocinnamic amide amphiphiles: substituent and solvent effects
Sign Up to like & getrecommendations! Published in 2019 at "Beilstein Journal of Nanotechnology"
DOI: 10.3762/bjnano.10.156
Abstract: Chiral nanostructures, such as α-helical proteins and double helix DNA, are widely found in biological systems and play a significant role in the biofunction of life. These structures are essentially fabricated through the covalent or… read more here.
Keywords: assembled nitrocinnamic; chiral nanostructures; self assembled; nanostructures self ... See more keywords