Syntheses of Group 5 Amide Amidinates and Their Reactions with Water: Different Reactivities of Nb(V) and Ta(V) Complexes.
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DOI: 10.1021/acs.inorgchem.2c02365
Abstract: Chemistries of Nb(V) and Ta(V) compounds are essentially identical as a result of lanthanide contraction. Hydrolysis of M(NMe2)5 (M = Nb, Ta), for example, yields [M(μ3-O)(NMe2)3]4 (M = Nb, 1; Ta, 2) reported earlier. The… read more here.
Keywords: mec nipr; water; ligand; amide amidinates ... See more keywords