Amide-assisted radical strategy: metal-free direct fluorination of arenes in aqueous media
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DOI: 10.1039/c7gc00356k
Abstract: A metal- and initiator-free direct fluorination of arenes with the assistance of an amide group is developed. This reaction proceeded under simple aqueous conditions with good functional group tolerance and ortho–para selectivity, and is highly… read more here.
Keywords: free direct; direct fluorination; metal; fluorination arenes ... See more keywords
Amide-Assisted Rearrangement of Hydroxyarylformimidoyl Chloride to Diarylurea
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DOI: 10.3390/molecules26216437
Abstract: A novel amide-assisted rearrangement reaction of hydroxybenzimidoyl chloride has been established for the efficient synthesis of 1,3-diphenylurea derivatives. A variety of electronically and sterically different 1,3-diphenylurea derivatives can be obtained in good to excellent yields,… read more here.
Keywords: assisted rearrangement; chloride diarylurea; rearrangement hydroxyarylformimidoyl; hydroxyarylformimidoyl chloride ... See more keywords