Monomeric zinc(II) amide complexes supported by bidentate, benzannulated phenanthridine amido ligands
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DOI: 10.1016/j.poly.2019.01.023
Abstract: Abstract The first examples of homoleptic zinc amides (1-Zn and 2-Zn) supported by chelating, benzannulated 4-amidophenanthridine ligands (L1, L2) are reported. The organometallic compounds were characterized fully both in solution (NMR, UV–Vis, electrochemistry, emission spectroscopy)… read more here.
Keywords: zinc amide; monomeric zinc; complexes supported; zinc ... See more keywords
Thiazoline Carbene-Cu(I)-Amide complexes: Efficient White Electroluminescence from Combined Monomer and Excimer Emission.
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DOI: 10.1021/acsami.2c00847
Abstract: Luminescent carbene-metal-amide complexes bearing group 11 metals (Cu, Ag, Au) have recently attracted great attention due to their exceptional emission efficiency and high radiative decay rates (kr). These materials provide a less costly alternative to… read more here.
Keywords: emission; amide complexes; electroluminescence; thiazoline carbene ... See more keywords
Mono- and dinuclear zirconocene(iv) amide complexes for the catalytic dehydropolymerisation of phenylsilane
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DOI: 10.1039/d2ra04955d
Abstract: The dehydropolymerisation of phenylsilane is investigated using group 4 metallocene amide complexes as catalysts. The dinuclear zirconocene amide complex Cp2Zr(NMe2)(μ-Me3SiC3SiMe3)Zr(NMe2)Cp2 (2) (Cp = η5-cyclopentadienyl) shows high activity in dehydrocoupling reactions, producing polyphenylsilanes with molecular weights… read more here.
Keywords: zirconocene amide; dinuclear zirconocene; amide complexes; dehydropolymerisation phenylsilane ... See more keywords