Ternary amide-hydride system: A study on LiAl(NH2)4-LiAlH4 interaction
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Alloys and Compounds"
DOI: 10.1016/j.jallcom.2019.03.234
Abstract: Abstract LiAl(NH2)4 is a ternary amide that readily decomposes to release ammonia at temperatures as low as ∼ 90 °C. Owing to such instability as compared to binary amides, we hypothesize that the dehydrogenation mechanism involving ternary amide-hydride… read more here.
Keywords: amide hydride; dehydrogenation; lial nh2; interaction ... See more keywords
Insights into the Rb-Mg-N-H System: an Ordered Mixed Amide/Imide Phase and a Disordered Amide/Hydride Solid Solution.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b03232
Abstract: The crystal structure of a mixed amide-imide phase, RbMgND2ND, has been solved in the orthorhombic space group Pnma ( a = 9.55256(31), b = 3.70772(11) and c = 10.08308(32) Å). A new metal amide-hydride solid… read more here.
Keywords: imide phase; amide hydride; chemistry; mixed amide ... See more keywords