A Scalar Relativistic DFT Study on the Complexation Behavior and Selective Separation of Th(IV)/U(VI) With Four Amide Ligands Containing N‐Heterocycles
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DOI: 10.1002/aoc.70131
Abstract: Achieving efficient separation of thorium and uranium is one of the main technical challenges for the nuclear fuel cycle of thorium‐based molten salt reactors. In this work, the scalar relativistic density functional theory (DFT) calculations… read more here.
Keywords: scalar relativistic; separation; amide ligands; complexation ... See more keywords
New bis(phosphine-amide) ligands: Oxidation, coordination and supramolecular chemistry
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DOI: 10.1016/j.poly.2017.04.028
Abstract: Abstract The synthesis of four new bis(phosphine-amide) ligands E{NHC( O)-4-C6H4PPh2}2, E = 1,4-C6H4, 1,3-C6H4, 1,4-C6H4(CH2)2 or 1,4-C6H10, is reported along with a preliminary study of their properties. The ligands are slowly oxidized in solution to give the… read more here.
Keywords: chemistry; phosphine amide; bis phosphine; c6h4pph2 ... See more keywords
Oxalamide/Amide Ligands: Enhanced and Copper-Catalyzed C-N Cross-Coupling for Triarylamine Synthesis.
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DOI: 10.1021/acs.orglett.2c02364
Abstract: Triarylamines are privileged core structures that are found in versatile optoelectronic materials. New methods are constantly being sought for their preparation. Herein, a new protocol for triarylamine synthesis is presented where a wide range of… read more here.
Keywords: amide ligands; copper; cross coupling; oxalamide amide ... See more keywords