Bench‐Stable Cobalt Pre‐Catalysts for Mild Hydrosilative Reduction of Tertiary Amides to Amines and Beyond
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DOI: 10.1002/cctc.201801605
Abstract: The readily synthesized and bench‐stable cobalt dichloride complex (dpephos)CoCl2 is employed as a pre‐catalyst for a diversity of silane additions to unsaturated organic molecules, including the normally challenging reduction of amides to amines. With regard… read more here.
Keywords: stable cobalt; cobalt; bench stable; hydrosilative reduction ... See more keywords
Reduction of Amides to Amines with Pinacolborane Catalyzed by Heterogeneous Lanthanum Catalyst La(CH2C6H4NMe2-o)3@SBA-15.
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DOI: 10.1021/acs.inorgchem.1c01531
Abstract: Hydroboration of amides is a useful synthetic strategy to access the corresponding amines. In this contribution, it was found that the supported lanthanum benzyl material La(CH2C6H4NMe2-o)3@SBA-15 was highly active for the hydroboration of primary, secondary,… read more here.
Keywords: reduction; amines pinacolborane; ch2c6h4nme2 sba; amides amines ... See more keywords
Primary amides to amines or nitriles: a dual role by a single catalyst.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc05856g
Abstract: We report a manganese-catalyzed hydrosilylative reduction of various primary amides to amines (25 examples). On simple modification of the reaction conditions such as in the presence of a catalytic amount of secondary amide, the same… read more here.
Keywords: nitriles dual; amines nitriles; single catalyst; amides amines ... See more keywords