Iron-Catalyzed Sulfonylthiocyanation of α,β-Unsaturated Amides/Esters via the Insertion of Sulfur Dioxide.
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DOI: 10.1021/acs.orglett.2c02954
Abstract: An iron-catalyzed four-component sulfonylthiocyanation between α,β-unsaturated amides/esters, TMSNCS, aryldiazonium tetrafluoroborates, and sulfur dioxide (from SOgen) is demonstrated. This protocol is characterized by mild reaction conditions, good functional group compatibility, broad substrate scope, and good to… read more here.
Keywords: sulfonylthiocyanation unsaturated; sulfur dioxide; iron catalyzed; unsaturated amides ... See more keywords
Chemoselective acylation of 2-amino-8-quinolinol in the generation of C2-amides or C8-esters
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DOI: 10.1039/c7ra05287a
Abstract: Two different ways to carry out the chemoselective acylation of 2-amino-8-quinolinol with unique features to generate C2-amides or C8-esters were developed. The coupling reaction with a variety of carboxylic acids using EDCI and DMAP provided… read more here.
Keywords: amino; amides esters; acylation amino; amino quinolinol ... See more keywords
Dynamic kinetic resolution of α-F-β-ketone amides (esters) via Ir/f-diaphos-catalyzed asymmetric hydrogenation
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DOI: 10.1039/d4qo00125g
Abstract: Highly reactive and highly stereoselective asymmetric hydrogenation of α-F-β-ketone amides (esters) via Ir/f-diaphos-catalyzed dynamic kinetic resolution is reported. read more here.
Keywords: via diaphos; diaphos catalyzed; amides esters; esters via ... See more keywords