Dehydration of primary amides to nitriles catalyzed by [CNC]-pincer hydrido cobalt(III) complexes
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DOI: 10.1016/j.catcom.2018.12.002
Abstract: Abstract The dehydration reactions from primary amides to nitriles were catalyzed by the [CNC]-pincer hydrido cobalt(III) complexes [(ortho-F4C6 CH N C10H6)Co(III)(H)(PMe3)2] (1), [(2,5-F2C6H2 CH N C10H6)Co(III)(H)(PMe3)2] (2) and [(2,4,5-F3C6H CH N C10H6)Co(III)(H)(PMe3)2] (3) as catalysts… read more here.
Keywords: iii; amides nitriles; hydrido cobalt; cobalt iii ... See more keywords
Dehydration of Amides to Nitriles under Conditions of a Catalytic Appel Reaction.
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DOI: 10.1021/acs.orglett.7b03862
Abstract: A highly expedient protocol for a catalytic Appel-type dehydration of amides to nitriles has been developed that employs oxalyl chloride and triethylamine along with triphenylphosphine oxide as a catalyst. The reactions are usually complete in… read more here.
Keywords: nitriles conditions; catalytic appel; conditions catalytic; dehydration amides ... See more keywords
Efficient New Protocols for Converting Primary Amides into Nitriles Initiated by P(NMe2)3, PCl3, or P(OPh)3
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DOI: 10.1021/acsomega.8b00544
Abstract: Three efficient and high-yielding procedures have been developed for the conversion of primary amides into nitriles, mediated by hitherto unexplored P(NMe2)3, PCl3, or P(OPh)3. The reactions were conducted under operationally simple and mild conditions and… read more here.
Keywords: efficient new; pcl3 oph; nme2 pcl3; amides nitriles ... See more keywords
Recent developments in dehydration of primary amides to nitriles
Sign Up to like & getrecommendations! Published in 2020 at "Organic chemistry frontiers"
DOI: 10.1039/d0qo00843e
Abstract: Dehydration of amides is an efficient, clean and fundamental route for the syntheses of nitriles in organic chemistry. The two imperative functional groups viz., amide and nitrile groups have been extensively discussed in the literature.… read more here.
Keywords: catalyzed dehydrations; recent developments; chemistry; developments dehydration ... See more keywords