Exploration of Ligand-Centered Hydride Transfer in La/Y-Catalyzed Deoxygenative Reduction of Tertiary Amides with Pinacolborane.
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DOI: 10.1021/acs.inorgchem.2c03793
Abstract: A number of rare-earth metals and actinides have proven to be active in a wide variety of atom-efficient transformations. As compared to the related organometallic catalysts, the detailed mechanisms for the rare-earth metal-catalyzed reactions remain… read more here.
Keywords: hydride transfer; deoxygenative reduction; amides pinacolborane; transfer ... See more keywords