Structure of non-symmetric lithium amidinate complexes prepared by addition of lithium amides to various nitriles
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DOI: 10.1016/j.jorganchem.2016.11.015
Abstract: Abstract Lithium amidinate complexes were prepared by direct reactions from various nitriles - R1-C N (R = Ph, n-Bu, t-Bu) and trimethylsilyl-substituted lithium amides - R2(Me3Si)NLi (R2 = Ph, 2,6-(CH3)2C6H3 (Dmp) and 2,6-[(CH3)2CH]2C6H3 (Dipp)). All the reactions proceed only… read more here.
Keywords: various nitriles; amidinate; amidinate complexes; lithium amidinate ... See more keywords
Syntheses and characterization of hepta-coordinated Group 4 amidinate complexes.
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DOI: 10.1039/c8dt02523a
Abstract: Tri-amidinate chloride complexes M[MeC(NiPr)2]3Cl [M = Zr (1), Hf (2)] have been prepared from MCl4 and lithium amidinate Li[MeC(NiPr)2]. The uncommon hepta-coordinated complexes Zr-Cl (1) and Hf-Cl (2) undergo metathesis reactions with 1 equiv. of… read more here.
Keywords: amidinate; syntheses characterization; hepta coordinated; characterization hepta ... See more keywords
Deposition of metallic silver from versatile amidinate precursors for use in functional materials
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DOI: 10.1177/17475198221075301
Abstract: Silver (Ag) amidinate metal organic decomposition precursors of the type: [Ag2((ArN)2C(H))2] (Ar = 2,6-dimethylphenyl (1), 2,6-diethylphenyl (2) and 2,6-diisopropylphenyl (3)) have been used for the first time in the deposition of Ag films on glass… read more here.
Keywords: metallic silver; silver; spectroscopy; amidinate ... See more keywords