Structure of non-symmetric lithium amidinate complexes prepared by addition of lithium amides to various nitriles
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2016.11.015
Abstract: Abstract Lithium amidinate complexes were prepared by direct reactions from various nitriles - R1-C N (R = Ph, n-Bu, t-Bu) and trimethylsilyl-substituted lithium amides - R2(Me3Si)NLi (R2 = Ph, 2,6-(CH3)2C6H3 (Dmp) and 2,6-[(CH3)2CH]2C6H3 (Dipp)). All the reactions proceed only… read more here.
Keywords: various nitriles; amidinate; amidinate complexes; lithium amidinate ... See more keywords
New amidinate complexes of indium(iii): promising CVD precursors for transparent and conductive In2O3 thin films.
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DOI: 10.1039/c7dt01280b
Abstract: For the first time, synthesis of two new amidinate-ligand comprising heteroleptic indium complexes, namely [InCl(amd)2] (1) and [InMe(amd)2] (2), via salt-metathesis and their detailed characterization is reported. For comparison, the earlier reported homoleptic tris-amidinate [In(amd)3]… read more here.
Keywords: thin films; amidinate complexes; new amidinate; spectroscopy ... See more keywords