Magnesium Ethoxide Promoted Conversion of Nitriles to Amidines and Its Application in 5,6-Dihydroimidazobenzoxazepine Synthesis.
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DOI: 10.1021/acs.orglett.8b00824
Abstract: Magnesium ethoxide has been shown to be a mild, safe, and scalable alternative to trimethylaluminum for the direct addition of amines to aryl nitriles to access cyclic amidines. A variety of electronically diverse oxa-, thia-,… read more here.
Keywords: magnesium ethoxide; nitriles amidines; amidines application; ethoxide promoted ... See more keywords