Zinc(II) complexes with uncommon aminal and hemiaminal ether derivatives: synthesis, structure, phosphatase activity and theoretical rationalization of ligand and complex formation
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DOI: 10.1039/c8nj01853g
Abstract: Condensation of N-(2-hydroxyethyl)ethylenediamine and pyridine-2-carbaldehyde in the presence of ZnX2 salts (X = ClO4−, Cl−, Br−, I−) generates four complexes, namely, [ZnL1Cl](ClO4) (1), [ZnL1Cl][ZnCl3(H2O)]·2H2O (2), [ZnL1Br][ZnBr3(H2O)]·2H2O (3), and [Zn(L2)3]I2 (4), where L1 and L2 are… read more here.
Keywords: ligand complex; formation; aminal hemiaminal; ligand ... See more keywords