Cp*Ir(iii)- and Cp*Rh(iii)-catalyzed C(sp2)–H amination of arenes using thioethers as directing groups
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DOI: 10.1039/d0qo01353f
Abstract: A mild and selective Cp*Ir(iii)- and Cp*Rh(iii)-catalyzed direct C(sp2)–H amination of arenes and three types of nitrene precursor reagents is reported, with the assistance of a thioether directing group. read more here.
Keywords: iii iii; sp2 amination; catalyzed sp2; iii catalyzed ... See more keywords
Facile synthesis of N-aryl phenothiazines and phenoxazines via Brønsted acid catalyzed C-H amination of arenes.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06730c
Abstract: N-Aryl phenothiazines and phenoxazines are of significant importance in various disciplines throughout academia and industry. The conventional synthetic strategy for the construction of these structures centers on the transition-metal-catalyzed cross-coupling of aryl halides with phenothiazines… read more here.
Keywords: amination arenes; facile synthesis; synthesis aryl; aryl phenothiazines ... See more keywords