Ti-Catalyzed and -Mediated Oxidative Amination Reactions.
Sign Up to like & getrecommendations! Published in 2021 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.1c00368
Abstract: ConspectusTitanium is an attractive metal for catalytic reaction development: it is earth-abundant, inexpensive, and generally nontoxic. However-like most early transition metals-catalytic redox reactions with Ti are difficult because of the stability of the high-valent TiIV… read more here.
Keywords: catalyzed mediated; mediated oxidative; oxidative amination; amination reactions ... See more keywords
Important Role of NH-Carbazole in Aryl Amination Reactions Catalyzed by 2-Aminobiphenyl Palladacycles
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DOI: 10.1021/acscatal.3c00075
Abstract: 2-Aminobiphenyl palladacycles are among the most successful precatalysts for Pd-catalyzed cross-coupling reactions, including aryl amination. However, the role of NH-carbazole, a byproduct of precatalyst activation, remains poorly understood. Herein, the mechanism of the aryl amination… read more here.
Keywords: reactions catalyzed; amination reactions; aryl amination; amination ... See more keywords
A combined experimental and theoretical study on the reactivity of nitrenes and nitrene radical anions
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DOI: 10.1038/s41467-021-27687-6
Abstract: Nitrene transfer reactions represent one of the key reactions to rapidly construct new carbon-nitrogen bonds and typically require transition metal catalysts to control the reactivity of the pivotal nitrene intermediate. Herein, we report on the… read more here.
Keywords: radical anions; nitrenes nitrene; reactivity; nitrene radical ... See more keywords
Cross-dehydrogenative coupling and oxidative-amination reactions of ethers and alcohols with aromatics and heteroaromatics
Sign Up to like & getrecommendations! Published in 2017 at "Chemical Science"
DOI: 10.1039/c7sc01045a
Abstract: This is a perspective on cross-dehydrogenative coupling reactions of aromatic and heteroaromatic systems with ethers and alcohols via metal or organic catalysis, and through uncatalyzed means, leading to C–C and C–N bond formation. read more here.
Keywords: oxidative amination; amination reactions; coupling oxidative; cross dehydrogenative ... See more keywords
LPdCl2(amine) complexes supported by terphenyl phosphanes: applications in aryl amination reactions.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01354a
Abstract: Despite the excellent catalytic properties display by NHC-Pd-PEPPSI complexes in cross-coupling, phosphane analogs have been barely screened. In this work, we report the synthesis and characterization of a series of LPdCl2(amine) complexes bearing dialkylterphenyl phosphanes… read more here.
Keywords: complexes supported; amine complexes; amination reactions; lpdcl2 amine ... See more keywords
Toolbox for α-amination reactions
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DOI: 10.2174/1385272825666210728101125
Abstract: In the past few years, the number of protocols for α-amination of carbonyl compounds has dramatically increased, highlighting the importance of this moiety. While some classical approaches continue to be used, supported by novel catalysts,… read more here.
Keywords: amination reactions; chemistry; toolbox amination;
Chitin-Derived Nanocatalysts for Reductive Amination Reactions
Sign Up to like & getrecommendations! Published in 2023 at "Materials"
DOI: 10.3390/ma16020575
Abstract: Chitin, the second most abundant biopolymer in the planet after cellulose, represents a renewable carbon and nitrogen source. A thrilling opportunity for the valorization of chitin is focused on the preparation of biomass-derived N-doped carbonaceous… read more here.
Keywords: nanocatalysts reductive; amination reactions; chitin derived; reductive amination ... See more keywords