Nondirected, Cu-Catalyzed sp3 C-H Aminations with Hydroxylamine-Based Amination Reagents: Catalytic and Mechanistic Studies.
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00003
Abstract: This work demonstrates the use of hydroxylamine-based amination reagents RSO2NH-OAc for the nondirected, Cu-catalyzed amination of benzylic C-H bonds. The amination reagents can be prepared on a gram scale, are benchtop stable, and provide benzylic… read more here.
Keywords: amination reagents; hydroxylamine based; based amination; mechanistic studies ... See more keywords
Phenothiazinimides: Atom-Efficient Electrophilic Amination Reagents
Sign Up to like & getrecommendations! Published in 2018 at "Organic Letters"
DOI: 10.1021/acs.orglett.8b00914
Abstract: Phenothiazinimides, a fairly unknown class of imines, were prepared and found to be very reactive as ultrasimple atom-efficient electrophilic amination reagents for phenols and indoles under metal-free conditions. read more here.
Keywords: atom efficient; amination reagents; electrophilic amination; phenothiazinimides atom ... See more keywords