Mechanistic study on silver-catalyzed direct amination of unactivated CH bond
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.01.006
Abstract: Abstract A systematic investigation has been conducted into the mechanism for the silver-catalyzed direct amination of unactivated C H bonds in triflamides by density functional theory (DFT). The present work is in favor of the… read more here.
Keywords: silver catalyzed; direct amination; mechanistic study; amination unactivated ... See more keywords
Cu-Catalyzed C(sp3) Amination of Unactivated Secondary Alkyl Iodides Promoted by Diaryliodonium Salts.
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DOI: 10.1021/acs.orglett.3c01216
Abstract: Herein, we describe the development of a copper-catalyzed C(sp3) amination of unactivated secondary alkyl iodides mediated by diaryliodonium salts. Our protocol is enabled by the intermediacy of aryl radical species that undergo halogen atom transfer… read more here.
Keywords: sp3 amination; alkyl iodides; amination unactivated; catalyzed sp3 ... See more keywords
Palladium-Catalyzed Oxidative Amination of Unactivated Olefins with Primary Aliphatic Amines.
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DOI: 10.1021/jacs.3c02114
Abstract: Direct coupling of unactivated olefins with primary alkylamines is considered to be an efficient but unknown method for the construction of complex amines. Herein we report a catalytic intermolecular oxidative amination of unactivated olefins with… read more here.
Keywords: oxidative amination; unactivated olefins; amination unactivated; primary aliphatic ... See more keywords