Production and analysis of stable microfluidic devices with tunable surface hydrophilicity via the in-situ tertiary-amine catalyzed Michael addition of a multifunctional thiol to a multifunctional acrylate
Sign Up to like & getrecommendations! Published in 2020 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2020.109482
Abstract: Abstract Poly(dimethylsiloxane) (PDMS) is one of the dominant polymeric hydrophobic materials that has been widely used in microfluidic devices. Here, we employed amine-catalyzed thiol-acrylate chemistry with hydrophilic and fluorinated acrylates to produce a wide range… read more here.
Keywords: acrylate; microfluidic devices; michael addition; surface ... See more keywords
Products Generated by Amine-Catalyzed Strand Cleavage at Apurinic/Apyrimidinic Sites in DNA: New Insights from a Biomimetic Nucleoside Model System.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical research in toxicology"
DOI: 10.1021/acs.chemrestox.1c00408
Abstract: Abasic sites are common in cellular and synthetic DNA. As a result, it is important to characterize the chemical fate of these lesions. Amine-catalyzed strand cleavage at abasic sites in DNA is an important process… read more here.
Keywords: strand; generated amine; catalyzed strand; strand cleavage ... See more keywords
Enantioselective Direct Synthesis of C3-Hydroxyalkylated Pyrrole via an Amine-Catalyzed Aldol/Paal-Knorr Reaction Sequence.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02922
Abstract: Creating functionality with chirality at position C3 of pyrrole is challenging. An operationally simple organocatalytic method has been developed to generate functionality with a chiral tertiary/quaternary stereocenter at position C3 of pyrrole. The process proceeds… read more here.
Keywords: paal knorr; reaction; amine catalyzed; knorr reaction ... See more keywords