Amine‐Catalyzed, α‐Iminyl Radical Cation‐Driven Organic Transformations
Sign Up to like & getrecommendations! Published in 2025 at "ChemCatChem"
DOI: 10.1002/cctc.202402132
Abstract: Aminocatalysis has become a robust and widely used synthetic strategy for the efficient synthesis of valuable molecules. In this context, considerable progress has been achieved in amine‐catalyzed transformations involving radial species, providing new opportunities and… read more here.
Keywords: amine catalyzed; radical cations; organic transformations; radical cation ... See more keywords
Amine‐Catalyzed Aldol Addition of Dihydroxyacetone for Bio‐Based Flame Retardants
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DOI: 10.1002/cctc.202501139
Abstract: A new catalytic method was developed for synthesizing a sustainable phosphorus‐based flame retardant (PFR) from dihydroxyacetone (DHA), a triose derived from hexoses or glycerol oxidation, e.g., for PUR applications. The study first investigates alkyl amine… read more here.
Keywords: amine catalyzed; based flame; dihydroxyacetone; aldol addition ... See more keywords
Production and analysis of stable microfluidic devices with tunable surface hydrophilicity via the in-situ tertiary-amine catalyzed Michael addition of a multifunctional thiol to a multifunctional acrylate
Sign Up to like & getrecommendations! Published in 2020 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2020.109482
Abstract: Abstract Poly(dimethylsiloxane) (PDMS) is one of the dominant polymeric hydrophobic materials that has been widely used in microfluidic devices. Here, we employed amine-catalyzed thiol-acrylate chemistry with hydrophilic and fluorinated acrylates to produce a wide range… read more here.
Keywords: acrylate; microfluidic devices; michael addition; surface ... See more keywords
Products Generated by Amine-Catalyzed Strand Cleavage at Apurinic/Apyrimidinic Sites in DNA: New Insights from a Biomimetic Nucleoside Model System.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical research in toxicology"
DOI: 10.1021/acs.chemrestox.1c00408
Abstract: Abasic sites are common in cellular and synthetic DNA. As a result, it is important to characterize the chemical fate of these lesions. Amine-catalyzed strand cleavage at abasic sites in DNA is an important process… read more here.
Keywords: strand; generated amine; catalyzed strand; strand cleavage ... See more keywords
Enantioselective Direct Synthesis of C3-Hydroxyalkylated Pyrrole via an Amine-Catalyzed Aldol/Paal-Knorr Reaction Sequence.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02922
Abstract: Creating functionality with chirality at position C3 of pyrrole is challenging. An operationally simple organocatalytic method has been developed to generate functionality with a chiral tertiary/quaternary stereocenter at position C3 of pyrrole. The process proceeds… read more here.
Keywords: paal knorr; reaction; amine catalyzed; knorr reaction ... See more keywords
Late-stage peptide modification and macrocyclization enabled by tertiary amine catalyzed tryptophan allylation
Sign Up to like & getrecommendations! Published in 2024 at "Chemical Science"
DOI: 10.1039/d4sc01244e
Abstract: Late-stage modification of peptides could potentially endow peptides with significant bioactivity and physicochemical properties, and thereby provide novel opportunities for peptide pharmaceutical studies. Since tryptophan (Trp) bears a unique indole ring residue and plays various… read more here.
Keywords: tertiary amine; amine catalyzed; late stage; modification ... See more keywords