Direct evidence of amine-metal reaction in epoxy systems: An in situ calorimetry study of the interphase formation
Sign Up to like & getrecommendations! Published in 2020 at "Progress in Organic Coatings"
DOI: 10.1016/j.porgcoat.2020.105769
Abstract: Abstract Epoxy resins are ubiquitously encountered in industrial applications as in adhesives and composites. The properties of epoxy-amine networks are directly impacted by the presence of metal (hydr-oxidized) surfaces, leading to a modification of their… read more here.
Keywords: interphase; formation; metal; amine metal ... See more keywords
Further insight on amine-metal reaction in epoxy systems
Sign Up to like & getrecommendations! Published in 2021 at "Surfaces and Interfaces"
DOI: 10.1016/j.surfin.2021.100959
Abstract: Abstract Among thermosetting polymers, epoxy resins are major components of adhesives, sealants, paints and composites. Polymerization is often achieved by reaction of epoxy monomers like DGEBA with amine hardeners such as DETA. Previous works showed… read more here.
Keywords: amine metal; insight amine; metal reaction; reaction epoxy ... See more keywords
Influence of Water on an Epoxy/Amine-Metal Interphase: A Combined DFT and Mixing Calorimetry Approach.
Sign Up to like & getrecommendations! Published in 2023 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c22431
Abstract: Epoxy-amine systems are ubiquitous in the field of industrial thermosetting polymers, often used in a moist atmosphere. In addition, previous studies showed amine-metal interactions through the formation of an interphase, with the formation of surface… read more here.
Keywords: water; epoxy amine; interphase; amine metal ... See more keywords