Volatility of amines for CO2 capture
Sign Up to like & getrecommendations! Published in 2017 at "International Journal of Greenhouse Gas Control"
DOI: 10.1016/j.ijggc.2017.01.001
Abstract: Abstract Volatility is a critical criterion for amine selection for CO 2 capture from low pressure gas streams. The Henry's law constant (H am ) in water of 24 novel amines, including 18 tertiary amines,… read more here.
Keywords: volatility amines; volatility; hindered amines; gas ... See more keywords
Rhodium-catalyzed formation of silylcarbamates from the reaction of secondary amines with CO2 and hydrosilanes
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.06.010
Abstract: Abstract The reaction of (4-methyl-pyridine-2-iloxy)dimethylsilane (NSiMe–H, 1) with [RhCl(coe)2]2 gives the rhodium(III) complex [Rh(Cl)(κ2-NSiMe)2] (2), which reacts with a stoichiometric amount of AgCF3CO2 to afford [Rh(κ2-CF3CO2)(κ2-NSiMe)2] (3). Complexes 2 and 3 have been fully characterized… read more here.
Keywords: amines co2; formation silylcarbamates; reaction secondary; secondary amines ... See more keywords
Formylation of Amines by CO2 Hydrogenation Using Preformed Co(II)/Nickel(II) Complexes.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01401
Abstract: Preparation of formamides by CO2 hydrogenation requires an efficient catalyst and temperatures around 100 °C or higher, but most catalysts reported so far incorporate rare and toxic precious metals. Five cobalt(II) or nickel(II) complexes with… read more here.
Keywords: formylation amines; hydrogenation; nickel complexes; co2 hydrogenation ... See more keywords
Hydroxyl Group-Regulated Active Nano-Pd/C Catalyst Generation via in Situ Reduction of Pd(NH3)xCly/C for N-Formylation of Amines with CO2/H2
Sign Up to like & getrecommendations! Published in 2017 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.7b00363
Abstract: The reductive N-formylation of amines using CO2 and hydrogen is a promising means of incorporating CO2 into value-added chemicals. To date, there has been a lack of heterogeneous catalyst systems that are sufficiently active and… read more here.
Keywords: formylation; formylation amines; hydroxyl group; catalyst ... See more keywords
Multifunctional 1,3-diphenylguanidine for the carboxylative cyclization of homopropargyl amines with CO2 under ambient temperature and pressure.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc07671a
Abstract: Herein, we report that 1,3-diphenylguanidine (DPG) could be utilized for the carboxylative cyclization of homopropargyl amines with CO2 under ambient temperature and pressure, in combination with AgSbF6, which enabled the synthesis of both chiral and… read more here.
Keywords: cyclization homopropargyl; co2 ambient; ambient temperature; homopropargyl amines ... See more keywords