Accessing Aliphatic Amines in C-C Cross-Couplings by Visible Light/Nickel Dual Catalysis.
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DOI: 10.1021/acs.orglett.1c01207
Abstract: A general aminoalkylation of aryl halides was developed, overcoming intolerance of free amines in nickel-mediated C-C coupling. This transformation features broad functional group tolerance and high efficiency. Taking advantage of the fast desilylation of α-silylamines… read more here.
Keywords: cross couplings; couplings visible; accessing aliphatic; visible light ... See more keywords