Catalytic Asymmetric Tandem Reaction of o-Alkynylbenzaldehydes, Amines, and Diazo Compounds.
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DOI: 10.1021/acs.orglett.1c02433
Abstract: An efficient asymmetric tandem reaction of o-alkynylbenzaldehydes, amines, and diazo compounds catalyzed by chiral silver imidodiphosphate has been established. Chiral 1,2-dihydroisoquinoline analogues have a tertiary stereocenter at the C1 position, and substituents at the C3… read more here.
Keywords: amines diazo; asymmetric tandem; tandem reaction; diazo compounds ... See more keywords