Catalytic dehydrogenation of amines to imines and the in-situ reduction of sulfoxides into sulfides
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2021.07.007
Abstract: Abstract The catalytic acceptorless dehydrogenation of primary amines into imines and H2 represents one of the most important organic transformations, and the in-situ utilization of the generated H2 for chemical reduction reactions has never been… read more here.
Keywords: dehydrogenation; dehydrogenation amines; amines imines; catalytic dehydrogenation ... See more keywords
Binuclear Ru(III)-Containing Polyoxometalate with Efficient Photocatalytic Activity for Oxidative Coupling of Amines to Imines.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03282
Abstract: A novel binuclear ruthenium-based polyoxometalate, K6H[{Ru2Cl(H2O)(CH3COO)2}{WO(H2O)}2(PW9O34)2]ยท14H2O (1), was successfully synthesized by the conventional hydrothermal method. Compound 1 was well-characterized by single-crystal X-ray diffraction, X-ray powder diffraction (PXRD), infrared (IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), electrospray… read more here.
Keywords: amines imines; spectroscopy; photocatalytic activity; oxidative coupling ... See more keywords
Visible-Light-Driven Oxidation of Amines to Imines in Air Catalyzed by Polyoxometalate-Tris(bipyridine)ruthenium Hybrid Compounds.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01243
Abstract: The development of visible-light photocatalysts for the selective oxidative coupling of amines to imines is an area of great interest. Herein, four hybrid compounds based on polyoxometalate anions and tris(bipyridine)ruthenium cations, Ru(bpy)3[M6O19] (M = Mo,… read more here.
Keywords: bipyridine ruthenium; amines imines; spectroscopy; hybrid compounds ... See more keywords
Visible Light Gold Nanocluster Photocatalyst: Selective Aerobic Oxidation of Amines to Imines
Sign Up to like & getrecommendations! Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.6b03509
Abstract: This work demonstrates the synthesis of an efficient photocatalyst, Au25(PPh3)10Cl2(SC3H6SiO3)5/TiO2, for selective oxidation of amines to imines. The photocatalyst is prepared via hydrolysis of Au25(PPh3)10Cl2[(SC3H6Si(OC2H5)3]5 nanoclusters in the presence of TiO2 support. The gold nanoclusters… read more here.
Keywords: oxidation; visible light; photocatalyst; oxidation amines ... See more keywords
Cobalt-catalyzed Synthesis of Homoallylic Amines from Imines and Terminal Alkenes
Sign Up to like & getrecommendations! Published in 2019 at "Chemistry Letters"
DOI: 10.1246/cl.190378
Abstract: Homoallylic amines are important synthetic targets in organic synthesis. Compared to other conventional allylation reactions using pre-functionalized allylic compounds, the allylation of imines usi... read more here.
Keywords: synthesis; synthesis homoallylic; amines imines; homoallylic amines ... See more keywords