Metal-free trans-hydroboration without a B-H bond: reactions of propargyl amines with Lewis acidic boranes.
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DOI: 10.1039/d2cc02687b
Abstract: The first alkyne trans-hydroboration reaction without a B-H bond was described. This was achieved by reactions of propargyl amines with Lewis acidic boranes under mild conditions. The mechanism involved borane-mediated alkyne activation and intramolecular hydride… read more here.
Keywords: reactions propargyl; without bond; propargyl amines; trans hydroboration ... See more keywords