Highly Selective Electrocatalytic Oxidation of Amines to Nitriles Assisted by Water Oxidation on Metal-Doped α-Ni(OH)2.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c05403
Abstract: Selective oxidation to synthesize nitriles is critical for feedstock manufacturing in the chemical industry. Current strategies typically involve substitutions of alkyl halides with toxic cyanides or the use of strong oxidation reagents (oxygen or peroxide)… read more here.
Keywords: amines nitriles; metal doped; oxidation; water oxidation ... See more keywords
Primary amides to amines or nitriles: a dual role by a single catalyst.
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DOI: 10.1039/c9cc05856g
Abstract: We report a manganese-catalyzed hydrosilylative reduction of various primary amides to amines (25 examples). On simple modification of the reaction conditions such as in the presence of a catalytic amount of secondary amide, the same… read more here.
Keywords: nitriles dual; amines nitriles; single catalyst; amides amines ... See more keywords
Recent advances in the electrochemical reactions of nitrogen-containing organic compounds
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DOI: 10.1039/d2ra04087e
Abstract: The electrochemical reaction of amines, nitriles, amides, nitroaromatics, and imines has been proven to be a valuable method for the synthesis of various nitrogen-containing organic compounds. Synthetic uses of electrochemical methods for organic transformations of… read more here.
Keywords: amines nitriles; electrochemical reactions; organic compounds; nitrogen containing ... See more keywords