Reactions of sulfenic acids with amines, thiols, and thiolates studied by quantum chemical calculations
Sign Up to like & getrecommendations! Published in 2020 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2020.112979
Abstract: Abstract Biological sensor molecules for oxidative stress often rely on the oxidation of thiols to sulfenic acid intermediates. How this transformation induces a physiological response often relies on the fate of sulfenic acid. Sulfenic acids… read more here.
Keywords: acids amines; amines thiols; reactions sulfenic; thiols thiolates ... See more keywords
Sulfonamide Synthesis through Electrochemical Oxidative Coupling of Amines and Thiols
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b02266
Abstract: Sulfonamides are key motifs in pharmaceuticals and agrochemicals, spurring the continuous development of novel and efficient synthetic methods to access these functional groups. Herein, we report an environmentally benign electrochemical method which enables the oxidative… read more here.
Keywords: sulfonamide synthesis; amines thiols; synthesis electrochemical; electrochemical oxidative ... See more keywords