Catalytic Aminomethylation of Aminobenzamides with Bis(N,N-dimethylamino)methane and Carbamides
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DOI: 10.1134/s1070363219020063
Abstract: An effective method was developed for the synthesis of acyclic aniline derivatives bearing carbamide fragments by the reaction of carbamides with ortho-, meta-, and para-aminobenzamides and bis(N,N-dimethylamino) methane in the presence of NiCl2·6H2O and SmCl3·6H2O… read more here.
Keywords: dimethylamino methane; catalytic aminomethylation; bis dimethylamino; aminobenzamides bis ... See more keywords
Catalytic Cycloaminomethylation of Aminobenzamides with 1,3-Bis[dimethylamino(methoxy)methyl]thiourea
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DOI: 10.1134/s1070363219030022
Abstract: Efficient methods of the synthesis of cyclophanes containing the thiourea moiety via the reaction of o-, m-, and p-aminobenzamides with 1,3-bis(dimethylaminomethyl)thiourea or 1,3-bis(methoxymethyl)thiourea using NiCl2·6H2O and SmCl3·6H2O as catalysts have been developed. read more here.
Keywords: cycloaminomethylation aminobenzamides; methoxy methyl; catalytic cycloaminomethylation; dimethylamino methoxy ... See more keywords