Quantum chemical rovibrational analysis of aminoborane and its isotopologues
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DOI: 10.1002/jcc.26893
Abstract: Aminoborane, H2NBH2 and its isotopologues, H2N10BH2, D2NBD2, and D2N10BD2, have been studied by high‐level ab initio methods. All calculations rely on multidimensional potential energy surfaces and dipole moment surfaces including high‐order mode coupling terms, which… read more here.
Keywords: chemical rovibrational; rovibrational analysis; aminoborane; analysis aminoborane ... See more keywords
Frustrated Lewis Pair Chelation and Reactivity of Complexed Parent Iminoborane and Aminoborane.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02535
Abstract: An intramolecular phosphine-borane frustrated Lewis pair (FLP) chelate, iPr2P(C6H4)BCy2 or PB (Cy = cyclohexyl), was used to coordinate aminoborane (H2BNH2) and iminoborane (HBNH) units via donor-acceptor stabilization. Attempts to induce dehydrogenation from these B-N adducts… read more here.
Keywords: iminoborane; aminoborane; lewis pair; frustrated lewis ... See more keywords