Sulfoxonium Ylides in Aminocatalysis: An Enantioselective Entry to Cyclopropane-Fused Chromanol Structures
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DOI: 10.1021/acs.orglett.2c02204
Abstract: The 1,1a,2,7b-tetrahydrocyclopropa[c]chromene, arising from fusion of chromane and cyclopropane rings is the core of medicinally relevant compounds. Engaging sulfoxonium ylides in enantioselective aminocatalytic reactions for the first time, a convenient entry to this scaffold is… read more here.
Keywords: enantioselective entry; cyclopropane; ylides aminocatalysis; aminocatalysis enantioselective ... See more keywords