Haloamines as Bifunctional Reagents for Oxidative Aminohalogenation of Maleimides.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c01052
Abstract: An unprecedented copper-catalyzed oxidative aminohalogenation of electron-deficient maleimides with secondary amines and NXS (X = Cl, Br, I) was developed, in which the N-X bonds generated in situ were used as difunctionalized reagents. The distinctive… read more here.
Keywords: bifunctional reagents; reagents oxidative; aminohalogenation; haloamines bifunctional ... See more keywords
Metal-Free Aminohalogenation of Quinones With Alkylamines and NXS at Room Temperature
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.917371
Abstract: A simple and practical strategy for intermolecular aminohalogenation of quinone with alkyl amines and NXS was developed, in which haloamines generated in situ were employed as bifunctional reagents. The reaction system is reliable, efficient and… read more here.
Keywords: alkylamines nxs; free aminohalogenation; aminohalogenation; metal free ... See more keywords