Organocatalytic Asymmetric Tandem α‐Aminooxylation–Henry Reactions for the Synthesis of 1,2‐Diols: Total Synthesis of (–)‐l‐threo‐Sphinganine
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DOI: 10.1002/ejoc.201701289
Abstract: A novel and rapid asymmetric syntheses of 1,2-diol derivatives anti- and syn-β,γ-dihydroxynitroalkanes via organocatalyzed tandem α-aminooxylation-Henry reactions are described. The targeted diol derivatives are synthesized in good yields, with excellent enantio- and low to moderate… read more here.
Keywords: aminooxylation henry; tandem aminooxylation; henry reactions; threo sphinganine ... See more keywords