Catalytic Intermolecular Carboamination of Unactivated Alkenes via Directed Aminopalladation.
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DOI: 10.1021/jacs.7b06520
Abstract: An intermolecular 1,2-carboamination of unactivated alkenes proceeding via a Pd(II)/Pd(IV) catalytic cycle has been developed. To realize this transformation, a cleavable bidentate directing group is used to control the regioselectivity of aminopalladation and stabilize the… read more here.
Keywords: carboamination unactivated; aminopalladation; intermolecular carboamination; reaction ... See more keywords