Polynuclear Cu4L4 Copper(II) Aminyl Radical Coordination Complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00785
Abstract: We describe the structural features and magnetic properties of two polynuclear copper(II) complexes containing a redox-active ligand. These neutral complexes each bear the formula RL4Cu4 (R = tBu, Me) with the ligand in a dianion-aminyl… read more here.
Keywords: copper aminyl; polynuclear cu4l4; aminyl radical; copper ... See more keywords
Copper-Catalyzed Aminoarylation of Alkenes via Aminyl Radical Addition and Aryl Migration.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c03973
Abstract: We describe a new strategy for aminoarylation of alkenes by copper-catalyzed smiles rearrangement using O-benzoylhydroxylamines as the amine reagent. This method affords various β-amino amide derivatives possessing a quaternary carbon center with wide functional group… read more here.
Keywords: copper catalyzed; alkenes via; catalyzed aminoarylation; aminyl radical ... See more keywords
Synthesis, crystallographic and spectroscopic characterization, and theoretical elucidation of an elusive aminyl radical containing a CuII-aminyl-iminosemiquinone complex.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d0cc07378d
Abstract: An elusive aminyl radical and an iminosemiquinone radical-coordinated square pyramidal Cu(ii) complex (1) have been isolated by the reaction between the noninnocent ligand H4LPy(AP) and Cu(ClO4)2·6H2O in the presence of Et3N and air as the… read more here.
Keywords: spectroscopic characterization; synthesis crystallographic; aminyl radical; elusive aminyl ... See more keywords