Crystalline Ammonium Peroxogermanate as a Waste-Free, Fully Recyclable Versatile Precursor for Germanium Compounds.
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DOI: 10.1021/acs.inorgchem.8b02747
Abstract: High, nearly 100%, yield synthesis of ammonium peroxogermanate (APG), (NH4)6[Ge6(μ-OO)6(μ-O)6(OH)6]·6H2O, is presented, and its crystal structure is determined by single crystal X-ray study. It comprises centrosymmetric hexanuclear peroxogermanate anions [Ge6(μ-OO)6(μ-O)6(OH)6]6- with six μ-oxo- and six… read more here.
Keywords: germanium oxide; crystalline ammonium; germanium; ammonium ... See more keywords