Kinetic stabilization allows structural analysis of a benzoborirene.
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DOI: 10.1039/d1cc06588b
Abstract: Formal reduction of (2-bromophenyl)chloro(2,2'',4,4'',6,6''-hexaisopropyl-[1,1':3',1''-terphenyl]-2'-yl)borane with tert-butyl lithium at low temperatures yields a highly strained benzoborirene that is kinetically stabilized by the bulky terphenyl substituent. The target compound withstands heating to 80 °C, and represents the… read more here.
Keywords: stabilization allows; analysis benzoborirene; structural analysis; kinetic stabilization ... See more keywords