A valence tautomeric cobalt-dioxolene complex with an anchoring group for prospective chemical grafting to metal oxides.
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DOI: 10.1039/d0dt03771k
Abstract: Here, we synthesized a valence tautomeric cobalt-dioxolene complex featuring a protected anchoring group. At room temperature, the complex reveals a nearly pure low-spin-Co(iii)-catecholate state in the solid state, but a nearly pure high-spin-Co(ii)-semiquinonate state in… read more here.
Keywords: anchoring group; dioxolene complex; cobalt dioxolene; tautomeric cobalt ... See more keywords