Photophysical and Chiroptical Properties of Europium(III) Enantiomers with Axially Chiral Ancillary Ligands
Sign Up to like & getrecommendations! Published in 2025 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202500257
Abstract: Chiral lanthanide(III) complexes with superior circularly polarized luminescence (CPL) properties, especially for the efficient chiral europium(III) complexes with high dissymmetry factor (glum) obtained by rational design of coordination ligands, are important in the field of… read more here.
Keywords: axially chiral; ancillary ligands; europium iii; iii enantiomers ... See more keywords
Synthesis and photoluminescent performance of novel europium (III) carboxylates with heterocyclic ancillary ligands
Sign Up to like & getrecommendations! Published in 2019 at "Rare Metals"
DOI: 10.1007/s12598-019-01261-y
Abstract: Five novel europium(III) complexes with 2-[4-(dibutylamino)-2-hydroxybenzoyl]benzoic acid (DAHB) as primary ligand and bathophenanthroline (batho), 2,2’-bipyridyl (bipy), 5,6-dimethyl-1,10-phenanthroline (dmph), 1,10-phenanthroline (phen) as ancillary ligands were synthesized via solution precipitation method. The structural formulae of synthesized complexes… read more here.
Keywords: europium iii; novel europium; spectroscopy; ancillary ligands ... See more keywords
Synthesis and investigation of enhanced luminescence of Ln(III)-complexes containing fluorinated β-diketone and oxygen donor ancillary ligands for efficient advanced displays
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Luminescence"
DOI: 10.1016/j.jlumin.2020.117255
Abstract: Abstract 2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedione (fod) fluorinated β-diketone had been used to prepare a series of Ln3+ (Eu or Tb) ternary complexes with monodentate ancillary ligands such as aqua, urea, triphenylphosphineoxide (TPPO) and pyridine-N-oxide (PNO). Prepared ternary materials… read more here.
Keywords: investigation; fod; fluorinated diketone; luminescence ... See more keywords
Enhanced Deep-Red Phosphorescence in Cyclometalated Iridium Complexes with Quinoline-Based Ancillary Ligands.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00670
Abstract: Compounds with good photoluminescence quantum yields (ΦPL) in the deep-red to near-infrared parts of the spectrum are desired for a variety of applications in optoelectronics, imaging, and sensing. However, in this region of the spectrum,… read more here.
Keywords: deep red; iridium complexes; ancillary ligands; cyclometalated iridium ... See more keywords
Emission Tuning of Heteroleptic Arylborane-Ruthenium(II) Complexes by Ancillary Ligands: Observation of Strickler-Berg-Type Relation.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01058
Abstract: Novel heteroleptic arylborane-ruthenium(II) complexes having a series of ancillary ligands L' ([Ru(B2bpy)L'2]2+) in CH3CN showed low-energy/intense metal-to-ligand charge transfer (MLCT)-type absorption and intense/long-lived emission compared to the reference complexes. The spectroscopic and photophysical properties of… read more here.
Keywords: ruthenium complexes; ancillary ligands; type; arylborane ruthenium ... See more keywords
Dibenzothiophene-platinated complexes: probing the effect of ancillary ligands on the photophysical performance.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt00349h
Abstract: Cyclometalation of dibenzothienyl-pyridine (HPyDBT) afforded a series of platinum(ii) complexes Pt(PyDBT)(L)Cl (L = DMSO, 1; P(p-C6H4-X)3 (X = H, 2; CF3, 3; OMe, 4; NPh2, 5); 1,3,5-triaza-7-phosphaadamantane, 6; 2,6-dimethylphenyl isocyanide, 7). Chelating bidentate LL ligands… read more here.
Keywords: probing effect; effect ancillary; dibenzothiophene platinated; complexes probing ... See more keywords
Syntheses and photocatalytic properties of three new d10-based coordination polymers: effects of metal centres and ancillary ligands
Sign Up to like & getrecommendations! Published in 2019 at "CrystEngComm"
DOI: 10.1039/c9ce01325c
Abstract: Three d10-based coordination polymers with three different nitrogen-based ancillary ligands have been synthesized and their photocatalytic properties were explored in the decomposition of methyl violet. read more here.
Keywords: d10 based; based coordination; coordination polymers; photocatalytic properties ... See more keywords
Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds†‡
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc04402d
Abstract: Migratory insertions of olefins into metal–oxygen bonds are elementary steps of important catalytic processes, but well characterised complexes that undergo this reaction are rare, and little information on the effects of ancillary ligands on such… read more here.
Keywords: bite angles; rhodium; oxygen bonds; insertion ... See more keywords
Facile Csp-Csp bond formation prompted by an electrophilic fluorinating reagent from bis(alkynyl) platinum complexes.
Sign Up to like & getrecommendations! Published in 2025 at "Dalton transactions"
DOI: 10.1039/d5dt00150a
Abstract: Electrophilic fluorination of bis(phenylacetylene)-platinum(II) complexes containing bipy or dppe as ancillary ligands at room temperature leads to Csp-Csp reductive elimination. In this regard, Selectfluor (N-chloromethyl-N'-fluorotriethylenediammonium bis(tetrafluoroborate)) was used in the reactions at room temperature, under… read more here.
Keywords: csp; ancillary ligands; bis; platinum complexes ... See more keywords
Cd(II) enantiomers embedding helices from 3D frameworks to 2D layers controlled by shapes of ancillary ligands
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2021.1898602
Abstract: Abstract Two pairs of chiral coordination polymers, [Cd2((R)-CBA)2(1,4-BMIB)]n (1-R ), [Cd2((R)-CBA)2(1,4-BMIB)]n (1-S ), {[Cd((R)-CBA)(1,3-BMIB)]·H2O}n (2-R ), and {[Cd((R)-CBA)(1,3-BMIB)]·H2O}n (2-S ) (H2CBA = 4-(1-carboxyethoxy) benzoic acid, 1,4-BMIB = 1,4-bis(2-methyl-1H-imidazol-1-yl)benzene, 1,3-BMIB = 1,3-bis(2-methyl-1H-imidazol-1-yl)benzene), were constructed from lactate… read more here.
Keywords: enantiomers embedding; embedding helices; shapes ancillary; bmib ... See more keywords
Synthesis and Photophysical Evaluation of Isoleptic Pt(II) and Pd(II) Complexes Utilizing N^N^N Ligands as Luminophoric Chelators with Different Ancillary Ligands
Sign Up to like & getrecommendations! Published in 2024 at "Inorganics"
DOI: 10.3390/inorganics12020058
Abstract: We herein report on the synthesis and structural characterization, as well as on the photophysical properties, of a series of isoleptic Pt(II) and Pd(II) complexes featuring tridentate N^N^N chelators as luminophores while bearing diverse ancillary… read more here.
Keywords: tbu; isoleptic complexes; photophysical evaluation; ancillary ligands ... See more keywords