Covalency between the uranyl ion and dithiophosphinate by sulfur K-edge X-ray absorption spectroscopy and density functional theory.
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DOI: 10.1107/s160057752101198x
Abstract: The dithiophosphinic acids (HS2PR2) have been used for the selective separation of trivalent actinides (AnIII) from lanthanides (LnIII) over the past decades. The substituents on the dithiophosphinic acids dramatically impact the separation performance, but the… read more here.
Keywords: covalency; dithiophosphinic acids; aniii lniii; edge ... See more keywords