Enantioselective Synthesis of Atropisomeric Anilides via Pd(II)-Catalyzed Asymmetric C-H Olefination.
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DOI: 10.1021/jacs.0c09400
Abstract: Atropisomeric anilides have received tremendous attention as a novel class of chiral compounds possessing restricted rotation around an N-aryl chiral axis. However, in sharp contrast to the well-studied synthesis of biaryl atropisomers, the catalytic asymmetric… read more here.
Keywords: catalyzed asymmetric; via catalyzed; atropisomeric anilides; synthesis atropisomeric ... See more keywords
para-Selective copper-catalyzed C(sp2)-H amidation/dimerization of anilides via a radical pathway.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/c9cc09824k
Abstract: Copper-catalyzed amidation/dimerization of anilides via regioselective C(sp2)-H functionalization is achieved. The para-selective amidation is accomplished on the anilide aromatic ring via a radical pathway leading to C-N bond formation in the presence of ammonium persulfate… read more here.
Keywords: dimerization anilides; anilides via; amidation dimerization; copper ... See more keywords