Providing a New Aniline Bioisostere through the Photochemical Production of 1-Aminonorbornanes.
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DOI: 10.1016/j.chempr.2018.10.017
Abstract: This report describes the photochemical conversion of aminocyclopropanes into 1-aminonorbornanes via formal [3+2] cycloadditions initiated by homolytic fragmentation of amine radical cation intermediates. Aligning with the modern movement toward sp 3 -rich motifs in drug… read more here.
Keywords: bioisostere photochemical; aniline bioisostere; photochemical production; production aminonorbornanes ... See more keywords