Anion-Induced Reversible Actuation of Squaramide-Crosslinked Polymer Gels
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DOI: 10.1021/acsami.2c11136
Abstract: Supramolecular anion binding to squaramide crosslinkers in poly(N,N-dimethylacrylamide) gel networks enhances swelling and allows reversible chemically driven actuation. The volume swelling ratio of the gels is shown to depend on both the type of anion… read more here.
Keywords: reversible actuation; anion induced; actuation; induced reversible ... See more keywords
Anion-π-Induced Room Temperature Phosphorescence from Emissive Charge-Transfer States.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c02678
Abstract: The burgeoning noncovalent interactions between π-acidic aromatic surfaces and anions have been recently shown to have unique functional relevance in anion transport, ion sensing, and organocatalysis. Despite its potential to instigate charge-transfer (CT) states, modulation… read more here.
Keywords: state; anion induced; charge transfer; triplet ... See more keywords
Unveiling anion-induced folding in tripodal imidazolium receptors by ion-mobility mass spectrometry.
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DOI: 10.1039/d1cc02818a
Abstract: The anion-induced folding of tripodal imidazolium receptors has been investigated by NMR spectroscopy, electrospray ionization ion mobility mass spectrometry and DFT calculations. Such folding can be switched by anion release upon collision induced dissociation. read more here.
Keywords: anion; folding tripodal; imidazolium receptors; induced folding ... See more keywords
Anion-induced disproportionation of Th(III) complexes to form Th(II) and Th(IV) products.
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DOI: 10.1039/d2cc01272c
Abstract: A new synthesis of Th(II) complexes has been identified involving addition of simple MX salts (M = Li, Na, K; X = H, Cl, Me, N3) to Cp''3ThIII [Cp'' = [C5H3(SiMe3)2] in the presence of… read more here.
Keywords: complexes form; disproportionation iii; iii complexes; anion induced ... See more keywords